Yes. Chevy HD's now use Class IV receiver. You will have to get either a 2 1/2 inch Ball Mount, or use an adapter. Then, the HD Hitch itself won't allow safety chains. You can do what is mentioned above, or do what I did. I got two Grade 5 Eye bolts, and washers and nuts. I bolted them onto the receiver holes, upside down. Now I have eye bolts to connect to.
Not sure safety chains are a good idea to start with.....if I lose my trailer, I don't want to lose my truck also, and I would via 'accordian' type movement if hitch comes loose. Plus, I have never heard of a hitch coming loose but the safety chains NOT coming loose. Yet every hitch uses them. Maybe I just don't get out enough, dunno.