I am not sure there is too much to know. Keep your rearview camera on to monitor the TOAD if you have one. As you said, don't back up. And depending on the system you are using, you will probably need to keep the TOAD straight with the RV to hook it up or unhook it. For the Blue Ox system I use, if you are turned very much it just won't release well to unhook it.
For me, the CR-V just tags along behind me and I just have to be a little more cautious than usual when making turns to be sure the TOAD clears curbs and such.
2014 Sunseeker 2860DS